Title: Phase structure and properties of poly(ethylene terephthalate)/polyethylene based on recycled materials
Author: Lei, Yong; Wu, Qinglin; Clemons, Craig M.; Guo, Weihong.
Source: Journal of applied polymer science. Vol. 113, no. 3 (Aug. 5, 2009): pages 1710-1719.
Description: Blends based on recycled high density polyethylene (R-HDPE) and recycled poly(ethylene terephthalate) (R-PET) were made through reactive extrusion. The effects of maleated polyethylene (PE-g-MA), triblock copolymer of styrene and ethylene/butylene (SEBS), and 4,40-methylenedi(phenyl isocyanate) (MDI) on blend properties were studied. The 2% PE-g-MA improved the compatibility of R-HDPE and R-PET in all blends toughened by SEBS. For the R-HDPE/R-PET (70/30 w/w) blend toughened by SEBS, the dispersed PET domain size was significantly reduced with use of 2% PE-g-MA, and the impact strength of the resultant blend doubled. For blends with R-PET matrix, all strengths were improved by adding MDI through extending the PET molecular chains. The crystalline behaviors of R-HDPE and R-PET in one-phase rich systems influenced each other. The addition of PE-g-MA and SEBS consistently reduced the crystalline level (χc) of either the R-PET or the R-HDPE phase and lowered the crystallization peak temperature (Τc) of R-PET. Further addition of MDI did not influence R-HDPE crystallization behavior but lowered the χc of R-PET in R-PET rich blends. The thermal stability of R-HDPE/R-PET 70/30 and 50/50 (w/w) blends were improved by chain-extension when 0.5% MDI was added.
Keywords: Polyethylene, recycling, blends, polyethylene terephthalate, recycled products, extrusion process, injection molding of plastics, butene, termperature, composite materials, mechanical properties, crystallization, HDPE, ethylenes, SEBS, strength, styrenes, thermal degradation
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Lei, Yong; Wu, Qinglin; Clemons, Craig M.; Guo, Weihong 2009. Phase structure and properties of poly(ethylene terephthalate)/high-density polyethylene based on recycled materials. Journal of applied polymer science. Vol. 113, no. 3 (Aug. 5, 2009): pages 1710-1719.
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